|
|
BtrI_[glutamyl-carrier_protein] + L-glutamate + ATP <=> L-glutamyl-[BtrI_L-glutamyl-carrier_protein] + ADP + phosphate
|
6.2.1.39
[butirosin acyl-carrier protein]---L-glutamate ligase
|
–
|
|
MetaCyc:
RXN-13213
|
|
|
|
butirosin_B <=> Butirosin_A
|
5.1.3
|
–
|
|
KEGG:
R08911
MetaCyc:
RXN-13219
|
|
|
|
4-(gamma-L-glutamylamino)butanoyl-[BtrI_L-glutamyl-carrier_protein] + O2 + FMNH2 <=> 4-(gamma-L-glutamylamino)-(S)-2-hydroxy-butanoyl-[BtrI_L-glutamyl-carrier_protein] + H2O + FMN + H+
|
1.14.14.13
4-(gamma-L-glutamylamino)butanoyl-[BtrI acyl-carrier protein] monooxygenase
|
–
|
|
MetaCyc:
RXN-13216
|
|
|
|
gamma-L-glutamyl-butirosin_B <=> butirosin_B + 5-oxoproline
|
4.3.2.6
gamma-L-glutamyl-butirosin B gamma-glutamyl cyclotransferase
|
–
|
|
BRENDA:
BR50209
KEGG:
R08910
MetaCyc:
RXN-13218
|
|
|
|
4-Aminobutyryl-[acp] + L-glutamate + ATP <=> 4-(gamma-L-glutamylamino)butanoyl-[BtrI_L-glutamyl-carrier_protein] + ADP + phosphate + H+
|
6.2.1.39
[butirosin acyl-carrier protein]---L-glutamate ligase
|
–
|
|
MetaCyc:
RXN-13215
|
|
|
|
4-(gamma-L-glutamylamino)-(S)-2-hydroxy-butanoyl-[BtrI_L-glutamyl-carrier_protein] + ribostamycin <=> gamma-L-glutamyl-butirosin_B + BtrI_[glutamyl-carrier_protein] + H+
|
2.3.2.19
ribostamycin:4-(gamma-L-glutamylamino)-(S)-2-hydroxybutanoyl-[BtrI acyl-carrier protein] 4-(gamma-L-glutamylamino)-(S)-2-hydroxybutanoate transferase
|
–
|
|
MetaCyc:
RXN-13217
|
|
|
|
L-glutamyl-[BtrI_L-glutamyl-carrier_protein] + H+ <=> 4-Aminobutyryl-[acp] + CO2
|
4.1.1.95
L-glutamyl-[BtrI acyl-carrier protein] decarboxylase
|
–
|
|
MetaCyc:
RXN-13214
|
|